Alkaloids from Papaver setigerum DC.

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Title:Alkaloids from Papaver setigerum DC.
Creators:
Slavík, Jiří
Slavíková, Leonora
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 61, 7, pp. 1047-1052
Uncontrolled Keywords:<i>Papaveraceae</i>, Setigerine, Benzylisoquinoline alkaloids, Setigeridine

Abstract

Two new benzylisoquinoline alkaloids of the papaverine type, setigerine (racemic α-methoxypapaverine, <strong>1b</strong>) and setigeridine (<strong>1c</strong>), were isolated from <i>Papaver setigerum</i> DC. as the minor constituents. Their structures were established by spectral data and X-ray crystallographic analysis. Papaverine (<strong>1a</strong>) was isolated as the major alkaloid of the plant (0.05 wt.%) besides of less amounts of morphine, codeine and rhoeadine. In a low yield, protopine, cryptopine, thebaine, rhoeagenine, and <i>N</i>-methylthebainium (as iodide) were obtained and small quantities of laudanosine, stylopine, isoboldine, scoulerine, papaverrubine A, B, C, D and E, coptisine, corytuberine, and magnoflorine were identified by thin layer chromatography.

Title:Alkaloids from Papaver setigerum DC.
Creators:
Slavík, Jiří
Slavíková, Leonora
Uncontrolled Keywords:<i>Papaveraceae</i>, Setigerine, Benzylisoquinoline alkaloids, Setigeridine
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:61
Number:7
Page Range:pp. 1047-1052
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19961047UNSPECIFIED
ID Code:1008
Item Type:Article
Deposited On:06 Feb 2009 17:05
Last Modified:06 Feb 2009 16:05

Citation

Slavík, Jiří; Slavíková, Leonora (1996) Alkaloids from Papaver setigerum DC. Collection of Czechoslovak Chemical Communications, 61 (7). pp. 1047-1052. ISSN 0010-0765

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