Bis(1,10-phenantroline)copper(II) Complexes. Refinement of the Crystal Structure of the Dithiocyanato-bis(1,10-phenanthroline)copper(II) Complex

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Title:Bis(1,10-phenantroline)copper(II) Complexes. Refinement of the Crystal Structure of the Dithiocyanato-bis(1,10-phenanthroline)copper(II) Complex
Creators:
Kabešová, Mária
Kožíšková, Zlatica
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 6, pp. 1269-1277

Abstract

[Cu(NCS)<sub>2</sub>(phen)<sub>2</sub>] possesses the orthorhombic structure <i>Pbcn</i> at room temperature; the elementary cell parameters are <i>a</i> = 1.3029(21), <i>b</i> = 0.9900(15), <i>c</i> = 1.7256(23) nm, <i>Z</i> = 4. The central atom has the pseudooctahedral CuN<sub>6</sub> coordination. The thiocyanate ligands are coordinated by the nitrogen atom in the equatorial plane of the coordination polyhedron. Each phenanthroline ligand in the coordination polyhedron coordinates one equatorial and one axial position. All the coordinating ligands possess the <i>cis</i> arrangement in the coordination sphere. The experimental results are correlated with published data of other bis(phenanthroline)copper(II) crystal structures.

Title:Bis(1,10-phenantroline)copper(II) Complexes. Refinement of the Crystal Structure of the Dithiocyanato-bis(1,10-phenanthroline)copper(II) Complex
Creators:
Kabešová, Mária
Kožíšková, Zlatica
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:6
Page Range:pp. 1269-1277
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19921269UNSPECIFIED
ID Code:104
Item Type:Article
Deposited On:06 Feb 2009 16:39
Last Modified:06 Feb 2009 15:40

Citation

Kabešová, Mária; Kožíšková, Zlatica (1992) Bis(1,10-phenantroline)copper(II) Complexes. Refinement of the Crystal Structure of the Dithiocyanato-bis(1,10-phenanthroline)copper(II) Complex. Collection of Czechoslovak Chemical Communications, 57 (6). pp. 1269-1277. ISSN 0010-0765

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