Application of Cyclic Chronopotentiometry to the Study of Slow Charge Transfer Reactions at the DME and the SMDE

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Title:Application of Cyclic Chronopotentiometry to the Study of Slow Charge Transfer Reactions at the DME and the SMDE
Creators:
Molina, Ángela
González, Joaquín
Serna, Carmen
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 61, 10, pp. 1432-1444
Uncontrolled Keywords:SMDE, Slow charge transfer reactions, Chronopotentiometry, DME

Abstract

In this work we apply cyclic chronopotentiometry to analyze charge transfer reactions at spherical electrodes, highlighting the influence of electrode curvature and the formation of amalgam on the potential-time response. Moreover, methods are proposed for determining the formal potential and the kinetic parameters of the electrode reaction. Equations obtained for the dropping mercury electrode are transformed to those corresponding to a static mercury drop electrode and a plane electrode.

Title:Application of Cyclic Chronopotentiometry to the Study of Slow Charge Transfer Reactions at the DME and the SMDE
Creators:
Molina, Ángela
González, Joaquín
Serna, Carmen
Uncontrolled Keywords:SMDE, Slow charge transfer reactions, Chronopotentiometry, DME
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:61
Number:10
Page Range:pp. 1432-1444
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19961432UNSPECIFIED
ID Code:1047
Item Type:Article
Deposited On:06 Feb 2009 17:06
Last Modified:06 Feb 2009 16:06

Citation

Molina, Ángela; González, Joaquín; Serna, Carmen (1996) Application of Cyclic Chronopotentiometry to the Study of Slow Charge Transfer Reactions at the DME and the SMDE. Collection of Czechoslovak Chemical Communications, 61 (10). pp. 1432-1444. ISSN 0010-0765

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