Symmetrical Tris(4,6-diamino-5-methylene-2-pyrimidones): New Building Blocks for Self-Assembly of Hollow Spherical Supramolecules Locked by Hydrogen Bonds

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Title:Symmetrical Tris(4,6-diamino-5-methylene-2-pyrimidones): New Building Blocks for Self-Assembly of Hollow Spherical Supramolecules Locked by Hydrogen Bonds
Creators:
Alexander, Daniel
Holý, Petr
Fiedler, Pavel
Havlas, Zdeněk
Závada, Jiří
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 61, 10, pp. 1464-1472
Uncontrolled Keywords:Pyrimidones, Hydrogen bonding, Self-assembly

Abstract

Concise synthesis of the tris(pyrimidones) <strong>1a,b </strong>is described. Molecular modeling study demonstrated that both the prepared models <strong>1a,b </strong>are capable of self-assembling under formation of spherical dimers locked by 18 hydrogen bonds. Extreme insolubility in all common solvents precluded investigation of the self-assembly in solution. Circumstantial evidence in favor of the self-assembly has been provided in the solid and gas phase.

Title:Symmetrical Tris(4,6-diamino-5-methylene-2-pyrimidones): New Building Blocks for Self-Assembly of Hollow Spherical Supramolecules Locked by Hydrogen Bonds
Creators:
Alexander, Daniel
Holý, Petr
Fiedler, Pavel
Havlas, Zdeněk
Závada, Jiří
Uncontrolled Keywords:Pyrimidones, Hydrogen bonding, Self-assembly
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:61
Number:10
Page Range:pp. 1464-1472
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19961464UNSPECIFIED
ID Code:1050
Item Type:Article
Deposited On:06 Feb 2009 17:06
Last Modified:06 Feb 2009 16:06

Citation

Alexander, Daniel; Holý, Petr; Fiedler, Pavel; Havlas, Zdeněk; Závada, Jiří (1996) Symmetrical Tris(4,6-diamino-5-methylene-2-pyrimidones): New Building Blocks for Self-Assembly of Hollow Spherical Supramolecules Locked by Hydrogen Bonds. Collection of Czechoslovak Chemical Communications, 61 (10). pp. 1464-1472. ISSN 0010-0765

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