Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions

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Title:Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions
Creators:
Adámek, František
Hájek, Milan
Janoušek, Zbyněk
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 6, pp. 1291-1298

Abstract

Relative reactivity of CH<sub>3</sub>CCl<sub>3</sub> and CF<sub>3</sub>CCl<sub>3</sub> measured in competitive addition reactions with 1-hexene in the presence of free radical initiators or Cu, Pd and Ru complexes was found to depend on the type of catalyst. The unusual course of the reaction has been found in the additions catalyzed with copper(I)-amine complexes where CH<sub>3</sub>CCl<sub>3</sub> in competition with CF<sub>3</sub>CCl<sub>3</sub> was completely unreactive. The results have been explained in terms of the change of reaction mechanism and compared with classical free radical initiation.

Title:Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions
Creators:
Adámek, František
Hájek, Milan
Janoušek, Zbyněk
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:6
Page Range:pp. 1291-1298
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19921291UNSPECIFIED
ID Code:107
Item Type:Article
Deposited On:06 Feb 2009 16:39
Last Modified:06 Feb 2009 15:40

Citation

Adámek, František; Hájek, Milan; Janoušek, Zbyněk (1992) Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions. Collection of Czechoslovak Chemical Communications, 57 (6). pp. 1291-1298. ISSN 0010-0765

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