Oxidation of Toluene Over V2O5-Sb2O3/TiO2 Catalysts. Enhancement of Selectivity Towards Benzoic Acid

[img]PDF - Authorized users only
Language: English
41Kb
Title:Oxidation of Toluene Over V2O5-Sb2O3/TiO2 Catalysts. Enhancement of Selectivity Towards Benzoic Acid
Creators:
Antol, Marcel
Kaszonyi, Alexander
Hronec, Milan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 61, 11, pp. 1675-1680
Uncontrolled Keywords:Benzoic acid, CO<sub>2</sub>, V<sub>2</sub>O<sub>5</sub>, Oxidation, Toluene

Abstract

The effect of reaction parameters, additives and cooxidants on the selectivity of toluene oxidation to benzoic acid in the vapor phase has been studied. The presence of ethanol as cooxidant in the reaction stream does not improve the selectivity of toluene oxidation towards partial oxidation products via methyl group oxidation. However, the presence of carbon dioxide has a positive effect on the selectivity to benzoic acid formation. The catalysts were characterized by temperature programmed reduction.

Title:Oxidation of Toluene Over V2O5-Sb2O3/TiO2 Catalysts. Enhancement of Selectivity Towards Benzoic Acid
Creators:
Antol, Marcel
Kaszonyi, Alexander
Hronec, Milan
Uncontrolled Keywords:Benzoic acid, CO<sub>2</sub>, V<sub>2</sub>O<sub>5</sub>, Oxidation, Toluene
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:61
Number:11
Page Range:pp. 1675-1680
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19961675UNSPECIFIED
ID Code:1072
Item Type:Article
Deposited On:06 Feb 2009 17:06
Last Modified:06 Feb 2009 16:06

Citation

Antol, Marcel; Kaszonyi, Alexander; Hronec, Milan (1996) Oxidation of Toluene Over V2O5-Sb2O3/TiO2 Catalysts. Enhancement of Selectivity Towards Benzoic Acid. Collection of Czechoslovak Chemical Communications, 61 (11). pp. 1675-1680. ISSN 0010-0765

Repository Staff Only: item control page