Polynuclear Cadmium Compounds Containing cis-[Co(en)2(OH)2]+ Ligands

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Title:Polynuclear Cadmium Compounds Containing cis-[Co(en)2(OH)2]+ Ligands
Creators:
Müller, Susanne
Thewalt, Ulf
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 2, pp. 257-264
Uncontrolled Keywords:Co complexes, Cd complexes, Polynuclear complexes, Molecular structures

Abstract

Polynuclear heterometallic compounds containing cobalt and cadmium were prepared by the reaction of CdCl<sub>2</sub> with salts of the <i>cis</i>-[Co(en)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>3+</sup> cation. X-Ray analyses of the tetranuclear Co<sub>2</sub>Cd<sub>2</sub> complex [Cd<sub>2</sub>(mi-Cl)Cl<sub>4</sub>{(OH)<sub>2</sub>Co(en)<sub>2</sub>}<sub>2</sub>]ClO<sub>4 </sub>(<strong>1</strong>) and the polymeric compound [[Cd(mi-Cl)-(H<sub>2</sub>O)<sub>2</sub>{(OH)<sub>2</sub>Co(en)<sub>2</sub>}]Cl<sub>2</sub>]<sub><i>n</i></sub> (<strong>2</strong>) confirm that the [Co(en)<sub>2</sub>(OH)<sub>2</sub>]<sup>+</sup> groups act as chelating ligands toward the Cd atoms. The Cd coordination octahedra are connected by a face in <strong>1</strong> and by corners in <strong>2</strong>.

Title:Polynuclear Cadmium Compounds Containing cis-[Co(en)2(OH)2]+ Ligands
Creators:
Müller, Susanne
Thewalt, Ulf
Uncontrolled Keywords:Co complexes, Cd complexes, Polynuclear complexes, Molecular structures
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:2
Page Range:pp. 257-264
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19970257UNSPECIFIED
ID Code:1112
Item Type:Article
Deposited On:06 Feb 2009 17:06
Last Modified:06 Feb 2009 16:06

Citation

Müller, Susanne; Thewalt, Ulf (1997) Polynuclear Cadmium Compounds Containing cis-[Co(en)2(OH)2]+ Ligands. Collection of Czechoslovak Chemical Communications, 62 (2). pp. 257-264. ISSN 0010-0765

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