Dynamics of Electrodiffusion Friction Probes. I. Shape-Dependent Potentiostatic Transient

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Title:Dynamics of Electrodiffusion Friction Probes. I. Shape-Dependent Potentiostatic Transient
Creators:
Wein, Ondřej
Sobolík, Václav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 3, pp. 397-419
Uncontrolled Keywords:Limiting diffusion current, Wall shear rate, Unsteady diffusion layer

Abstract

An exact theory is given of the voltage-step transient under limiting diffusion conditions for an electrodiffusion friction probe of arbitrary convex shape. The actual transient courses are given for the strip, circular, elliptic, triangular, and rectangular probes of any orientation with respect to the flow direction. A simple formula for any probe with a single working electrode of convex shape is suggested to facilitate the calibration of electrodiffusion probes based on the voltage-step transient.

Title:Dynamics of Electrodiffusion Friction Probes. I. Shape-Dependent Potentiostatic Transient
Creators:
Wein, Ondřej
Sobolík, Václav
Uncontrolled Keywords:Limiting diffusion current, Wall shear rate, Unsteady diffusion layer
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:3
Page Range:pp. 397-419
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19970397UNSPECIFIED
ID Code:1127
Item Type:Article
Deposited On:06 Feb 2009 17:06
Last Modified:06 Feb 2009 16:06

Citation

Wein, Ondřej; Sobolík, Václav (1997) Dynamics of Electrodiffusion Friction Probes. I. Shape-Dependent Potentiostatic Transient. Collection of Czechoslovak Chemical Communications, 62 (3). pp. 397-419. ISSN 0010-0765

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