Adsorption Effects of Thiourea at the Hg Electrode in Water-Dimethyl Sulfoxide Mixtures on Zn(II) Reduction

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Title:Adsorption Effects of Thiourea at the Hg Electrode in Water-Dimethyl Sulfoxide Mixtures on Zn(II) Reduction
Creators:
Marczewska, Barbara
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 6, pp. 843-848
Uncontrolled Keywords:Mixed solvent, Mercury electrode, Solvation shell, Electroreduction

Abstract

The adsorption of thiourea (TU) and the kinetics of Zn(II) reduction at mercury electrode from the solutions of NaClO<sub>4 </sub>in 10 and 70 vol.% dimethyl sulfoxide (DMSO) at various concentrations of TU have been studied. The obtained results indicate that in the process of Zn(II) electroreduction the dominant role is played by the structure of the primary solvation shell of Zn(II).

Title:Adsorption Effects of Thiourea at the Hg Electrode in Water-Dimethyl Sulfoxide Mixtures on Zn(II) Reduction
Creators:
Marczewska, Barbara
Uncontrolled Keywords:Mixed solvent, Mercury electrode, Solvation shell, Electroreduction
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:6
Page Range:pp. 843-848
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19970843UNSPECIFIED
ID Code:1166
Item Type:Article
Deposited On:06 Feb 2009 17:07
Last Modified:06 Feb 2009 16:07

Citation

Marczewska, Barbara (1997) Adsorption Effects of Thiourea at the Hg Electrode in Water-Dimethyl Sulfoxide Mixtures on Zn(II) Reduction. Collection of Czechoslovak Chemical Communications, 62 (6). pp. 843-848. ISSN 0010-0765

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