Synthesis of 2α,3α-Epoxy-9β-benzoyloxy-β-agarofuran and 2,3-Dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran

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Title:Synthesis of 2α,3α-Epoxy-9β-benzoyloxy-β-agarofuran and 2,3-Dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran
Creators:
Nan, Fajun
Liu, Lijun
Xiong, Zhaoming
Chen, Yonggang
Li, Tongshuang
li, Yulin
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 7, pp. 1089-1094
Uncontrolled Keywords:2,3-Dehydro-4β,9β-dihydroxy-β-dihydroagarofuran, 2,3-Dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran, 2α,3α-Epoxy-9β-benzoyloxy-β-agarofuran

Abstract

The first stereoselective synthesis of 2α,3α-epoxy-9β-benzoyloxy-β-agarofuran (<strong>3</strong>) and 2,3-dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran (<strong>4</strong>) from (-)-carvone in 13 steps, respectively, has been described. In addition, the synthesis of 2,3-dehydro-4β,9β-dihydroxy-β-dihydroagarofuran (<strong>13</strong>) has also been reported. By the reduction of <strong>4</strong> to give <strong>13</strong>, the 4β,12-epoxy configuration of <strong>4</strong> was established.

Title:Synthesis of 2α,3α-Epoxy-9β-benzoyloxy-β-agarofuran and 2,3-Dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran
Creators:
Nan, Fajun
Liu, Lijun
Xiong, Zhaoming
Chen, Yonggang
Li, Tongshuang
li, Yulin
Uncontrolled Keywords:2,3-Dehydro-4β,9β-dihydroxy-β-dihydroagarofuran, 2,3-Dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran, 2α,3α-Epoxy-9β-benzoyloxy-β-agarofuran
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:7
Page Range:pp. 1089-1094
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19971089UNSPECIFIED
ID Code:1188
Item Type:Article
Deposited On:06 Feb 2009 17:07
Last Modified:06 Feb 2009 16:07

Citation

Nan, Fajun; Liu, Lijun; Xiong, Zhaoming; Chen, Yonggang; Li, Tongshuang; li, Yulin (1997) Synthesis of 2α,3α-Epoxy-9β-benzoyloxy-β-agarofuran and 2,3-Dehydro-4β,12-epoxy-9β-benzoyloxy-β-dihydroagarofuran. Collection of Czechoslovak Chemical Communications, 62 (7). pp. 1089-1094. ISSN 0010-0765

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