Restricted Intramolecular Energy Flow in Large Molecules. Heterogeneous and Enzyme Catalysis

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Title:Restricted Intramolecular Energy Flow in Large Molecules. Heterogeneous and Enzyme Catalysis
Creators:
Šolc, Milan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 8, pp. 1150-1158
Uncontrolled Keywords:Intramolecular energy flow, Heavy atoms, Heterogeneous catalysis, Enzyme catalysis

Abstract

The free intramolecular energy flow can be restricted by the presence of a heavy atom in the molecule. As a result of this restriction, adsorbed molecules bonded on the metal surface and/or substrate molecules in the enzyme-substrate complex with a metal atom near the binding site can have a higher vibrational energy than the surroundings. The reaction rate is then enhanced by this energy localization.

Title:Restricted Intramolecular Energy Flow in Large Molecules. Heterogeneous and Enzyme Catalysis
Creators:
Šolc, Milan
Uncontrolled Keywords:Intramolecular energy flow, Heavy atoms, Heterogeneous catalysis, Enzyme catalysis
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:8
Page Range:pp. 1150-1158
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19971150UNSPECIFIED
ID Code:1195
Item Type:Article
Deposited On:06 Feb 2009 17:07
Last Modified:06 Feb 2009 16:07

Citation

Šolc, Milan (1997) Restricted Intramolecular Energy Flow in Large Molecules. Heterogeneous and Enzyme Catalysis. Collection of Czechoslovak Chemical Communications, 62 (8). pp. 1150-1158. ISSN 0010-0765

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