Insertion of Hydrogen and/or Lithium Into Cesium Tungsten Bronze

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Title:Insertion of Hydrogen and/or Lithium Into Cesium Tungsten Bronze
Creators:
Bludská, Jana
Vondrák, Jiří
Jakubec, Ivo
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 8, pp. 1177-1184
Uncontrolled Keywords:Coinsertion tungsten bronzes, Hydrogen insertion, Lithium insertion

Abstract

Hydrogen and/or lithium insertion into hexagonal cesium tungsten bronze, Cs<sub>0.3</sub>WO<sub>3</sub>, was studied using voltammetric and a.c. admittance methods. The close values of stoichiometric coefficients for hydrogen and/or lithium in coinsertion bronzes as well as the close values of diffusion coefficients <i>D</i><sub>H</sub> and <i>D</i><sub>Li</sub> are ascribed to a lattice distortion caused by large cesium species which influence both equilibrium and the mobility of inserting species regardless of their different chemical nature.

Title:Insertion of Hydrogen and/or Lithium Into Cesium Tungsten Bronze
Creators:
Bludská, Jana
Vondrák, Jiří
Jakubec, Ivo
Uncontrolled Keywords:Coinsertion tungsten bronzes, Hydrogen insertion, Lithium insertion
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:8
Page Range:pp. 1177-1184
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19971177UNSPECIFIED
ID Code:1198
Item Type:Article
Deposited On:06 Feb 2009 17:07
Last Modified:06 Feb 2009 16:07

Citation

Bludská, Jana; Vondrák, Jiří; Jakubec, Ivo (1997) Insertion of Hydrogen and/or Lithium Into Cesium Tungsten Bronze. Collection of Czechoslovak Chemical Communications, 62 (8). pp. 1177-1184. ISSN 0010-0765

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