Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst

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Title:Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst
Creators:
Dobrovolná, Zuzana
Červený, Libor
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 62, 9, pp. 1497-1502
Uncontrolled Keywords:Alkene hydrogenation, Transfer hydrogenation, Ammonium formate

Abstract

Competitive hydrogenation of alkenes (cyclohexene, hex-1-ene, hept-1-ene, oct-1-ene) and dienes (octa-1,7-diene, cyclohexa-1,3-diene) was carried out by catalytic hydrogen transfer from ammonium formate on palladium in methanol. The adsorptivity and reactivity of the hydrocarbons decreased in the series: cyclic diene > linear diene > linear 1-alkene > cyclic alkene.

Title:Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst
Creators:
Dobrovolná, Zuzana
Červený, Libor
Uncontrolled Keywords:Alkene hydrogenation, Transfer hydrogenation, Ammonium formate
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:62
Number:9
Page Range:pp. 1497-1502
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19971497UNSPECIFIED
ID Code:1225
Item Type:Article
Deposited On:06 Feb 2009 17:07
Last Modified:06 Feb 2009 16:07

Citation

Dobrovolná, Zuzana; Červený, Libor (1997) Competitive Hydrogenation of Unsaturated Hydrocarbons by Hydrogen Transfer from Ammonium Formateon a Palladium Catalyst. Collection of Czechoslovak Chemical Communications, 62 (9). pp. 1497-1502. ISSN 0010-0765

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