Vanadyl Phosphate and Its Intercalation Reactions. A Review

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Title:Vanadyl Phosphate and Its Intercalation Reactions. A Review
Creators:
Kalousová, Jaroslava
Votinský, Jiří
Beneš, Ludvík
Melánová, Klára
Zima, Vítězslav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 63, 1, pp. 1-19
Uncontrolled Keywords:Intercalation, Vanadyl phosphate, Layered compounds

Abstract

The structure of the layered α<sub>I</sub>-VOPO<sub>4</sub>, VOPO<sub>4</sub>·2H<sub>2</sub>O, and their intercalation reactions are discussed. These reactions are divided into two groups. The first includes intercalation reactions of molecular guests which proceed as acid-base processes between the host layered lattice (Lewis acid) and a donor atom of the guest (base). Interaction of water molecules, alcohols, amines, carboxylic acids and their derivatives, heterocyclic N- and S-donors, and complex compounds with vanadyl phosphates is discussed. Vanadyl phosphate, in particular vanadyl phosphate dihydrate can also undergo the second type of the reactions which involves the reduction of a fraction of vanadium(V) atoms to vanadium(IV) with concomitant intercalation of alkylammonium, hydronium or mono- and divalent metal cations to counterbalance the induced negative layer charge. A review with 76 references.

Title:Vanadyl Phosphate and Its Intercalation Reactions. A Review
Creators:
Kalousová, Jaroslava
Votinský, Jiří
Beneš, Ludvík
Melánová, Klára
Zima, Vítězslav
Uncontrolled Keywords:Intercalation, Vanadyl phosphate, Layered compounds
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:63
Number:1
Page Range:pp. 1-19
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19980001UNSPECIFIED
ID Code:1268
Item Type:Article
Deposited On:06 Feb 2009 17:08
Last Modified:06 Feb 2009 16:08

Citation

Kalousová, Jaroslava; Votinský, Jiří; Beneš, Ludvík; Melánová, Klára; Zima, Vítězslav (1998) Vanadyl Phosphate and Its Intercalation Reactions. A Review. Collection of Czechoslovak Chemical Communications, 63 (1). pp. 1-19. ISSN 0010-0765

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