Solubility and Thermodynamic Transfer Functions of Cesium Dianilinetetraisothiocyanatochromate(III)

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Title:Solubility and Thermodynamic Transfer Functions of Cesium Dianilinetetraisothiocyanatochromate(III)
Creators:
Holba, Vladislav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 63, 3, pp. 293-298
Uncontrolled Keywords:Solubility, Chromium complexes, Transfer functions, Cesium salts

Abstract

The solubilities of cesium dianilinetetraisothiocyanatochromate(III) in water as well as in aqueous methanol, isopropyl alcohol, <i>tert</i>-butyl alcohol and acetonitrile were measured as a function of temperature and solvent composition. The Gibbs energies, enthalpies and entropies of transfer of the salt from water to the given solvents have been evaluated from experimental data. The contribution of [Cr(C<sub>6</sub>H<sub>5</sub>NH<sub>2</sub>)<sub>2</sub>(NCS)<sub>4</sub>]<sup>-</sup> ion to the Gibbs energy of transfer of the investigated salt has been calculated using the tetraphenylarsonium tetraphenylborate (TATB) reference electrolyte assumption.

Title:Solubility and Thermodynamic Transfer Functions of Cesium Dianilinetetraisothiocyanatochromate(III)
Creators:
Holba, Vladislav
Uncontrolled Keywords:Solubility, Chromium complexes, Transfer functions, Cesium salts
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:63
Number:3
Page Range:pp. 293-298
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19980293UNSPECIFIED
ID Code:1296
Item Type:Article
Deposited On:06 Feb 2009 17:08
Last Modified:06 Feb 2009 16:08

Citation

Holba, Vladislav (1998) Solubility and Thermodynamic Transfer Functions of Cesium Dianilinetetraisothiocyanatochromate(III). Collection of Czechoslovak Chemical Communications, 63 (3). pp. 293-298. ISSN 0010-0765

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