Structure of Another Phase of (1-Phenyl-3-(2-[(2-aminoethyl)amino]ethylimino)-1-buten-1-olato-O,N,N',N")palladium(II) Perchlorate

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Title:Structure of Another Phase of (1-Phenyl-3-(2-[(2-aminoethyl)amino]ethylimino)-1-buten-1-olato-O,N,N',N")palladium(II) Perchlorate
Creators:
Kratochvíl, Bohumil
Ondráček, Jan
Novotný, Jiří
Macíček, Josef
Haber, Václav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 1, pp. 85-92

Abstract

The structure of the β-phase of (1-phenyl-3-(2-[(2-aminoethyl)amino]-ethylimino)-1-buten-1-olato-<i>O,N,N',N"</i>) palladium(II) perchlorate, β-[Pd(baden)]ClO<sub>4</sub>, was solved by the heavy atom method and refined anisotropically to <i>R</i> = 0.035 for 11 226 unique observed reflections. The title compound is orthorhombic, <i>a</i> = 14.152(2), <i>b</i> = 12.507(1), <i>c</i> = 20.012(2) Å, <i>Pca</i>2<sub>1</sub>, <i>Z</i> = 8. The structure contains two symmetrically independent molecules both formed by two five-membered and two six-membered rings (one of them is phenyl) and disordered perchlorate anion. The crystal packing is predominantly given by electrostatic interactions accompanied by weak hydrogen bonding among nitrogens and perhlorate oxygens. No structural significant differences between α- and β-phases were found.

Title:Structure of Another Phase of (1-Phenyl-3-(2-[(2-aminoethyl)amino]ethylimino)-1-buten-1-olato-O,N,N',N")palladium(II) Perchlorate
Creators:
Kratochvíl, Bohumil
Ondráček, Jan
Novotný, Jiří
Macíček, Josef
Haber, Václav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:1
Page Range:pp. 85-92
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19920085UNSPECIFIED
ID Code:13
Item Type:Article
Deposited On:06 Feb 2009 16:35
Last Modified:06 Feb 2009 15:36

Citation

Kratochvíl, Bohumil; Ondráček, Jan; Novotný, Jiří; Macíček, Josef; Haber, Václav (1992) Structure of Another Phase of (1-Phenyl-3-(2-[(2-aminoethyl)amino]ethylimino)-1-buten-1-olato-O,N,N',N")palladium(II) Perchlorate. Collection of Czechoslovak Chemical Communications, 57 (1). pp. 85-92. ISSN 0010-0765

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