A New Host Lattice Built of the Werner-Type Copper(I,II) Cyanide Complex Involving a Macrocyclic Ligand

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Title:A New Host Lattice Built of the Werner-Type Copper(I,II) Cyanide Complex Involving a Macrocyclic Ligand
Creators:
Yuge, Hidetaka
Soma, Takayoshi
Miyamoto, Takeshi Ken
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 63, 5, pp. 622-627
Uncontrolled Keywords:Clathrates, Crystal structure, Macrocyclic ligands, Copper(I,II) cyanide, Copper complexes, Werner complex host

Abstract

Crystals of a new clathrate [Cu<sup>II</sup>(hmtd)Cu<sup>I</sup>(CN)<sub>3</sub>]·CH<sub>2</sub>Cl<sub>2</sub> were afforded from a Me<sub>2</sub>CO-EtOH-CH<sub>2</sub>Cl<sub>2</sub> solution of a macrocyclic complex Cu<sup>II</sup>(hmtd)Cu<sup>I</sup>(CN)<sub>3</sub>·2 H<sub>2</sub>O (hmtd = 5,7,7,12,14,14-hexamethyl- 1,4,8,11-tetraazacyclotetradeca- 4,11-diene). It crystallizes in the monoclinic space group <i>P2<sub>1</sub>/n</i>, <i>a</i> = 7.936(5), <i>b</i> = 18.717(4), <i>c</i> = 17.783(6) Å, β = 98.55(4)°, <i>Z</i> = 4, <i>R</i> = 0.0558 for 1 870 reflections. Unprecedentedly, only one of the three nitrogen-ends of a Cu<sup>I</sup>(CN)<sub>3</sub> moiety is coordinated to the square-pyramidal Cu(II) center. The guest CH<sub>2</sub>Cl<sub>2 </sub>molecules are captured in the channel between the potlid-shaped [Cu<sup>II</sup>(hmtd)Cu<sup>I</sup>(CN)<sub>3</sub>] molecules. <p>

Title:A New Host Lattice Built of the Werner-Type Copper(I,II) Cyanide Complex Involving a Macrocyclic Ligand
Creators:
Yuge, Hidetaka
Soma, Takayoshi
Miyamoto, Takeshi Ken
Uncontrolled Keywords:Clathrates, Crystal structure, Macrocyclic ligands, Copper(I,II) cyanide, Copper complexes, Werner complex host
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:63
Number:5
Page Range:pp. 622-627
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19980622UNSPECIFIED
ID Code:1327
Item Type:Article
Deposited On:06 Feb 2009 17:08
Last Modified:06 Feb 2009 16:08

Citation

Yuge, Hidetaka; Soma, Takayoshi; Miyamoto, Takeshi Ken (1998) A New Host Lattice Built of the Werner-Type Copper(I,II) Cyanide Complex Involving a Macrocyclic Ligand. Collection of Czechoslovak Chemical Communications, 63 (5). pp. 622-627. ISSN 0010-0765

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