Ultrafast Nonadiabatic Dynamics. Theoretical Study of Femtosecond Electron Transfer Processes

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Title:Ultrafast Nonadiabatic Dynamics. Theoretical Study of Femtosecond Electron Transfer Processes
Creators:
Jortner, Joshua
Bixon, Mordechai
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 63, 8, pp. 1285-1294
Uncontrolled Keywords:Electron transfer, Ultrafast femtosecond dynamics, Franck-Condon quasicontinuum

Abstract

This paper addresses the conceptual framework of femtosecond nonadiabatic dynamics involving electron transfer processes on the time scale of nuclear motion. Coupling and relaxation of a manifold of doorway states into a weakly correlated Franck-Condon quasicontinuum reflects the extension of the validity range of nonadiabatic dynamics for large values of the electronic coupling, transcendenting the vibrational period of nuclear motion. The theory is applied to ultrafast femtosecond electron transfer processes in solution.

Title:Ultrafast Nonadiabatic Dynamics. Theoretical Study of Femtosecond Electron Transfer Processes
Creators:
Jortner, Joshua
Bixon, Mordechai
Uncontrolled Keywords:Electron transfer, Ultrafast femtosecond dynamics, Franck-Condon quasicontinuum
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:63
Number:8
Page Range:pp. 1285-1294
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19981285UNSPECIFIED
ID Code:1380
Item Type:Article
Deposited On:06 Feb 2009 17:09
Last Modified:06 Feb 2009 16:09

Citation

Jortner, Joshua; Bixon, Mordechai (1998) Ultrafast Nonadiabatic Dynamics. Theoretical Study of Femtosecond Electron Transfer Processes. Collection of Czechoslovak Chemical Communications, 63 (8). pp. 1285-1294. ISSN 0010-0765

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