Catalytic Activity of 4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl in Homogeneous Electrooxidation of Hydroxylamine

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Title:Catalytic Activity of 4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl in Homogeneous Electrooxidation of Hydroxylamine
Creators:
Xia, He
Li, Hu Lin
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 63, 12, pp. 1994-2000
Uncontrolled Keywords:Catalytic electrooxidation, Hydroxylamine, Cyclic voltammetry, 4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl, Electrochemistry

Abstract

4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl (<strong>1</strong>) shows catalytic electroactivity in homogeneous oxidation of hydroxylamine on a glassy carbon electrode. Kinetic parameters of the electrode reaction were measured and an catalytic reaction mechanism for the electrooxidation was proposed. Possible application of electrocatalytic activity of <strong>1 </strong>in determination hydroxylamine was also discussed.

Title:Catalytic Activity of 4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl in Homogeneous Electrooxidation of Hydroxylamine
Creators:
Xia, He
Li, Hu Lin
Uncontrolled Keywords:Catalytic electrooxidation, Hydroxylamine, Cyclic voltammetry, 4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl, Electrochemistry
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:63
Number:12
Page Range:pp. 1994-2000
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19981994UNSPECIFIED
ID Code:1438
Item Type:Article
Deposited On:06 Feb 2009 17:09
Last Modified:06 Feb 2009 16:09

Citation

Xia, He; Li, Hu Lin (1998) Catalytic Activity of 4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl in Homogeneous Electrooxidation of Hydroxylamine. Collection of Czechoslovak Chemical Communications, 63 (12). pp. 1994-2000. ISSN 0010-0765

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