Formation of a Double Salt and Mixed Crystals in the Ca(HCOO)2-Cd(HCOO)2-H2O System

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Title:Formation of a Double Salt and Mixed Crystals in the Ca(HCOO)2-Cd(HCOO)2-H2O System
Creators:
Vassileva, Violeta Z.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 63, 12, pp. 2036-2043
Uncontrolled Keywords:Calcium, Calcium/cadmium formate mixed crystals, Cadmium, Calcium/cadmium formate double salt, Solubility diagrams

Abstract

By solubility method in the Ca(HCOO)<sub>2</sub>-Cd(HCOO)<sub>2</sub>-H<sub>2</sub>O system at 25 and 50 °C, the formation of a double salt CaCd(HCOO)<sub>4 </sub>and mixed crystals Ca<sub>1-<i>x</i></sub>Cd<sub><i>x</i></sub>(HCOO)<sub>2 </sub>was established. The double salt formation is explained by the electronic configuration of the metal ions involved. Formation of the mixed crystals, possessing the α-Ca(HCOO)<sub>2 </sub>structure, is attributed to the ability of the Cd<sup>2+ </sup>ions to accept the coordination environment, characteristic of the Ca<sup>2+ </sup>ions in α-Ca(HCOO)<sub>2</sub>. <p>

Title:Formation of a Double Salt and Mixed Crystals in the Ca(HCOO)2-Cd(HCOO)2-H2O System
Creators:
Vassileva, Violeta Z.
Uncontrolled Keywords:Calcium, Calcium/cadmium formate mixed crystals, Cadmium, Calcium/cadmium formate double salt, Solubility diagrams
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:63
Number:12
Page Range:pp. 2036-2043
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19982036UNSPECIFIED
ID Code:1443
Item Type:Article
Deposited On:06 Feb 2009 17:09
Last Modified:06 Feb 2009 16:09

Citation

Vassileva, Violeta Z. (1998) Formation of a Double Salt and Mixed Crystals in the Ca(HCOO)2-Cd(HCOO)2-H2O System. Collection of Czechoslovak Chemical Communications, 63 (12). pp. 2036-2043. ISSN 0010-0765

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