Autoxidation vs Hydrolysis in 16α-Acyloxy Steroids

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Title:Autoxidation vs Hydrolysis in 16α-Acyloxy Steroids
Creators:
Slavíková, Barbora
Kasal, Alexander
Buděšínský, Miloš
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 64, 7, pp. 1125-1134
Uncontrolled Keywords:<sup>1</sup>H NMR spectroscopy, Mass spectrometry, Steroids, Ketones, Oxidation, Neighbouring group participation

Abstract

Some enolizable α-hydroxy ketones are extremely susceptible to oxidation with traces of air in a reaction vessel. Autoxidation can be used in synthesis of oxo acids or diacids and their derivatives. Yet alkaline hydrolysis of the substrate is possible though under strictly air-free conditions.

Title:Autoxidation vs Hydrolysis in 16α-Acyloxy Steroids
Creators:
Slavíková, Barbora
Kasal, Alexander
Buděšínský, Miloš
Uncontrolled Keywords:<sup>1</sup>H NMR spectroscopy, Mass spectrometry, Steroids, Ketones, Oxidation, Neighbouring group participation
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:64
Number:7
Page Range:pp. 1125-1134
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19991125UNSPECIFIED
ID Code:1544
Item Type:Article
Deposited On:06 Feb 2009 17:10
Last Modified:06 Feb 2009 16:10

Citation

Slavíková, Barbora; Kasal, Alexander; Buděšínský, Miloš (1999) Autoxidation vs Hydrolysis in 16α-Acyloxy Steroids. Collection of Czechoslovak Chemical Communications, 64 (7). pp. 1125-1134. ISSN 0010-0765

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