Oxidizability and Structure of Lactams

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Title:Oxidizability and Structure of Lactams
Creators:
Burda, Jaroslav
Lánská, Božena
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 58, 2, pp. 354-364

Abstract

The radical-initiated chain oxidation of five- to nine-membered lactams with molecular oxygen has been studied by the quantum-chemical method AM1. It has been confirmed that the reaction is controlled by its propagation step. The kinetic length of the oxidation chains correlates with the energy of formation of the lactam radical by abstraction of hydrogen from the methylene group adjacent to nitrogen atom. With five- to eight-membered rings the reaction is symmetry-forbidden.

Title:Oxidizability and Structure of Lactams
Creators:
Burda, Jaroslav
Lánská, Božena
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:58
Number:2
Page Range:pp. 354-364
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19930354UNSPECIFIED
ID Code:158
Item Type:Article
Deposited On:06 Feb 2009 16:58
Last Modified:06 Feb 2009 15:58

Citation

Burda, Jaroslav; Lánská, Božena (1993) Oxidizability and Structure of Lactams. Collection of Czechoslovak Chemical Communications, 58 (2). pp. 354-364. ISSN 0010-0765

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