Planar Tetracoordinate Carbon in Organoboron Compounds: ab initio Computational Study

[img]PDF - Authorized users only
Language: English
176Kb
Title:Planar Tetracoordinate Carbon in Organoboron Compounds: ab initio Computational Study
Creators:
Gribanova, Tatyana N.
Minyaev, Ruslan M.
Minkin, Vladimir I.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 64, 11, pp. 1780-1789
Uncontrolled Keywords:Boranes, <i>Ab initio</i> calculations, Boron, Planar tetracoordinate carbon, 1,2-Diboraspiro[2.2]- pent-4-ene

Abstract

<i>Ab initio</i> MP2(full)/6-311++G** calculations revealed that 1,2-diboraspiro[2.2]pent-4-ene (<strong>11</strong>) and two of its isomers <strong>14</strong> and <strong>15</strong> possess stable structures with planar tetracoordinate carbon. These compounds and some of their derivatives, <strong>21</strong> and <strong>22</strong>, can be regarded as the first computationally found organoboron compounds with the planar tetracoordinate carbon. <p>

Title:Planar Tetracoordinate Carbon in Organoboron Compounds: ab initio Computational Study
Creators:
Gribanova, Tatyana N.
Minyaev, Ruslan M.
Minkin, Vladimir I.
Uncontrolled Keywords:Boranes, <i>Ab initio</i> calculations, Boron, Planar tetracoordinate carbon, 1,2-Diboraspiro[2.2]- pent-4-ene
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:64
Number:11
Page Range:pp. 1780-1789
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19991780UNSPECIFIED
ID Code:1595
Item Type:Article
Deposited On:06 Feb 2009 17:10
Last Modified:06 Feb 2009 16:11

Citation

Gribanova, Tatyana N.; Minyaev, Ruslan M.; Minkin, Vladimir I. (1999) Planar Tetracoordinate Carbon in Organoboron Compounds: ab initio Computational Study. Collection of Czechoslovak Chemical Communications, 64 (11). pp. 1780-1789. ISSN 0010-0765

Repository Staff Only: item control page