Deformation of the Adamantane Skeleton by Substitution: Crystal Structure of 1-Methylsulfonyladamantane

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Title:Deformation of the Adamantane Skeleton by Substitution: Crystal Structure of 1-Methylsulfonyladamantane
Creators:
Tinant, Bernard
Declercq, Jean-Paul
Exner, Otto
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 58, 2, pp. 373-377

Abstract

The crystals of 1-methylsulfonyladamantane are monoclinic, space group <i>P2</i><sub>1</sub>/<i>a</i>, with <i>a</i> = 11.094(3), <i>b</i> = 7.668(2), <i>c</i> = 13.161(3) Å, β = 101.74(2)<sup>0</sup>, <i>V</i> = 1 096.1(5) Å<sup>3</sup>, <i>Z</i> = 4, <i>D</i><sub>x</sub> = 1.29 g cm <sup>-3</sup>, MoK<sub>α</sub>, λ = 0.71069 Å, μ = 2.65 cm<sup>-1</sup>, <i>F</i>(000) = 456, <i>T</i> = 291 K, the final <i>R</i> value is 0.036 for 1 834 observed reflections. For this compound and from literature data, the bond angles of adamantane derivatives are briefly discussed: the angle on the substituted C(1) atom depends clearly on the substituent but the available figures are still rather imprecise.

Title:Deformation of the Adamantane Skeleton by Substitution: Crystal Structure of 1-Methylsulfonyladamantane
Creators:
Tinant, Bernard
Declercq, Jean-Paul
Exner, Otto
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:58
Number:2
Page Range:pp. 373-377
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19930373UNSPECIFIED
ID Code:160
Item Type:Article
Deposited On:06 Feb 2009 16:58
Last Modified:06 Feb 2009 15:58

Citation

Tinant, Bernard; Declercq, Jean-Paul; Exner, Otto (1993) Deformation of the Adamantane Skeleton by Substitution: Crystal Structure of 1-Methylsulfonyladamantane. Collection of Czechoslovak Chemical Communications, 58 (2). pp. 373-377. ISSN 0010-0765

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