Effect of the Structure of Unsaturated Hydrocarbons and Alcohols on Their Reactivity and Adsorptivity in Hydrogenation

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Title:Effect of the Structure of Unsaturated Hydrocarbons and Alcohols on Their Reactivity and Adsorptivity in Hydrogenation
Creators:
Kačer, Petr
Novák, Petr
Červený, Libor
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 1, pp. 9-16
Uncontrolled Keywords:Unsaturated hydrocarbons, Competitive hydrogenation, Palladium catalyst, Selectivity, Heterogeneous catalysis, Adsorptivity, Reactivity, Unsaturated alcohols

Abstract

Competitive hydrogenations of unsaturated hydrocarbons and unsaturated alcohols using a palladium supported catalyst, were studied under atmospheric pressure at 25 °C. From the acquired data and from the hydrogenation of each individual substrate, kinetic and adsorption parameters were determined. It was found that the hydroxyl group position relative to the double bond has no significant effect on the reactivity of the studied unsaturated alcohols; however, it has a major effect on their adsorptivity. Reactivity and adsorptivity of unsaturated hydrocarbons depended on the double bond position in substrates. <p>

Title:Effect of the Structure of Unsaturated Hydrocarbons and Alcohols on Their Reactivity and Adsorptivity in Hydrogenation
Creators:
Kačer, Petr
Novák, Petr
Červený, Libor
Uncontrolled Keywords:Unsaturated hydrocarbons, Competitive hydrogenation, Palladium catalyst, Selectivity, Heterogeneous catalysis, Adsorptivity, Reactivity, Unsaturated alcohols
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:1
Page Range:pp. 9-16
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000009UNSPECIFIED
ID Code:1618
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Kačer, Petr; Novák, Petr; Červený, Libor (2000) Effect of the Structure of Unsaturated Hydrocarbons and Alcohols on Their Reactivity and Adsorptivity in Hydrogenation. Collection of Czechoslovak Chemical Communications, 65 (1). pp. 9-16. ISSN 0010-0765

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