Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

[img]PDF - Authorized users only
Language: English
117Kb
Title:Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten
Creators:
Pavlík, Ivan
Pavlišta, Martin
Jacob, Klaus
Pietzsch, Claus
Lébl, Tomáš
Vinklárek, Jaromír
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 1, pp. 23-34
Uncontrolled Keywords:Carbonyl complexes, Ferrocenes, Metallocenes, (Dimethylaminomethyl)ferrocene, Molybdenum, Donor-acceptor complexes, IR spectroscopy, UV-VIS spectroscopy, Mössbauer spectroscopy, Tungsten, NMR spectroscopy

Abstract

(Dimethylaminomethyl)ferrocene (HFcR, R = CH<sub>2</sub>NMe<sub>2</sub>) reacts with Mo(CO)<sub>6</sub> and W(CO)<sub>6</sub> under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcR·M(CO)<sub>5</sub> (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mössbauer spectroscopy. <p>

Title:Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten
Creators:
Pavlík, Ivan
Pavlišta, Martin
Jacob, Klaus
Pietzsch, Claus
Lébl, Tomáš
Vinklárek, Jaromír
Uncontrolled Keywords:Carbonyl complexes, Ferrocenes, Metallocenes, (Dimethylaminomethyl)ferrocene, Molybdenum, Donor-acceptor complexes, IR spectroscopy, UV-VIS spectroscopy, Mössbauer spectroscopy, Tungsten, NMR spectroscopy
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:1
Page Range:pp. 23-34
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000023UNSPECIFIED
ID Code:1620
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Pavlík, Ivan; Pavlišta, Martin; Jacob, Klaus; Pietzsch, Claus; Lébl, Tomáš; Vinklárek, Jaromír (2000) Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten. Collection of Czechoslovak Chemical Communications, 65 (1). pp. 23-34. ISSN 0010-0765

Repository Staff Only: item control page