Synthesis of 2,2'-Bipyridines with Axially Chiral 1,1'-Binaphthalene Units

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Title:Synthesis of 2,2'-Bipyridines with Axially Chiral 1,1'-Binaphthalene Units
Creators:
Hodačová, Jana
Stibor, Ivan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 1, pp. 83-98
Uncontrolled Keywords:Biaryls, Bipyridines, <i>N</i>-Ligands, Copper complexes, Binaphthalenes, Chiral ligands, Axial chirality

Abstract

Synthesis of a series of novel 2,2'-bipyridine-based ligands bearing the axially chiral 2,2'-dialkoxy-1,1'-binaphthalene units is presented. The oxydimethylene, amidomethylene and amido spacers have been utilised to link the 3 or 3,3' positions of the binaphthalene skeleton with the 6 or 6,6' positions of the 2,2'-bipyridine moieties. The ligands have been synthesised in both racemic and enantiomerically pure <i>R</i> forms. <p>

Title:Synthesis of 2,2'-Bipyridines with Axially Chiral 1,1'-Binaphthalene Units
Creators:
Hodačová, Jana
Stibor, Ivan
Uncontrolled Keywords:Biaryls, Bipyridines, <i>N</i>-Ligands, Copper complexes, Binaphthalenes, Chiral ligands, Axial chirality
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:1
Page Range:pp. 83-98
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000083UNSPECIFIED
ID Code:1625
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Hodačová, Jana; Stibor, Ivan (2000) Synthesis of 2,2'-Bipyridines with Axially Chiral 1,1'-Binaphthalene Units. Collection of Czechoslovak Chemical Communications, 65 (1). pp. 83-98. ISSN 0010-0765

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