Kinetics of Collision Processes in Dilute Noble Gases

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Title:Kinetics of Collision Processes in Dilute Noble Gases
Creators:
Kalus, René
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 2, pp. 141-160
Uncontrolled Keywords:Gas-phase chemistry, Kinetics, Clusters, Argon, Noble gases, Reaction mechanisms, van der Waals interactions

Abstract

Kinetics of collision processes is analyzed for dilute noble gases within a linear approximation. Dilute gas is treated as a chemically reacting mixture of dimers and monomers. Two elementary reaction models are analyzed employing theoretical rate constants calculated recently from quasiclassical trajectories. Stability of stationary states and relaxation of small concentration perturbations are treated in terms of linearized kinetic equations. The results obtained are generalized for heavier noble gases (neon to xenon). Helium is, because of quantum nature, analyzed separately. <p>

Title:Kinetics of Collision Processes in Dilute Noble Gases
Creators:
Kalus, René
Uncontrolled Keywords:Gas-phase chemistry, Kinetics, Clusters, Argon, Noble gases, Reaction mechanisms, van der Waals interactions
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:2
Page Range:pp. 141-160
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000141UNSPECIFIED
ID Code:1631
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Kalus, René (2000) Kinetics of Collision Processes in Dilute Noble Gases. Collection of Czechoslovak Chemical Communications, 65 (2). pp. 141-160. ISSN 0010-0765

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