Diferrocenylphosphine: A Facile Synthesis and Its Use to Prepare Chiral Phosphines

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Title:Diferrocenylphosphine: A Facile Synthesis and Its Use to Prepare Chiral Phosphines
Creators:
Guillaneux, Denis
Martiny, Lars
Kagan, Henri B.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 5, pp. 717-728
Uncontrolled Keywords:<i>P</i>-Ligands, Asymmetric hydrogenation, Chiral ferrocenyldiphosphines, DIOP, Ferrocenes, Metallocenes, Phosphines, Diferrocenylphosphine

Abstract

Diferrocenylphosphine-borane has been synthesized in three steps from monolithio- ferrocene. This compound may be transformed into the corresponding phosphide which is a nucleophilic reagent allowing to introduce the diferrocenylphosphino grouping in organic compounds. Several chiral diphosphines related to DIOP have been synthesized by this method. The corresponding rhodium complexes are catalysts in the hydrogenation of various C=C double bonds. <p>

Title:Diferrocenylphosphine: A Facile Synthesis and Its Use to Prepare Chiral Phosphines
Creators:
Guillaneux, Denis
Martiny, Lars
Kagan, Henri B.
Uncontrolled Keywords:<i>P</i>-Ligands, Asymmetric hydrogenation, Chiral ferrocenyldiphosphines, DIOP, Ferrocenes, Metallocenes, Phosphines, Diferrocenylphosphine
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:5
Page Range:pp. 717-728
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000717UNSPECIFIED
ID Code:1674
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Guillaneux, Denis; Martiny, Lars; Kagan, Henri B. (2000) Diferrocenylphosphine: A Facile Synthesis and Its Use to Prepare Chiral Phosphines. Collection of Czechoslovak Chemical Communications, 65 (5). pp. 717-728. ISSN 0010-0765

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