Synthesis and 1H NMR Complexation Study of Thiacalix[4]arene Tetraacetates

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Title:Synthesis and 1H NMR Complexation Study of Thiacalix[4]arene Tetraacetates
Creators:
Lhoták, Pavel
Šťastný, Václav
Zlatušková, Petra
Stibor, Ivan
Michlová, Veronika
Tkadlecová, Marcela
Havlíček, Jaroslav
Sýkora, Jan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 5, pp. 757-771
Uncontrolled Keywords:Alkylation, Thiacalixarenes, Calixarenes, X-Ray diffraction, Alkali metal cations, Complexation, NMR spectroscopy

Abstract

Alkylation of thiacalix[4]arenes with ethyl bromoacetate led to high yields (≈60%) of corresponding tetraacetates in various conformations (cone, partial cone, 1,3-alternate) depending strictly on the carbonate (Na, K, Cs) used for the reaction. The complexation ability of new compounds was studied by <sup>1</sup>H NMR. <p>

Title:Synthesis and 1H NMR Complexation Study of Thiacalix[4]arene Tetraacetates
Creators:
Lhoták, Pavel
Šťastný, Václav
Zlatušková, Petra
Stibor, Ivan
Michlová, Veronika
Tkadlecová, Marcela
Havlíček, Jaroslav
Sýkora, Jan
Uncontrolled Keywords:Alkylation, Thiacalixarenes, Calixarenes, X-Ray diffraction, Alkali metal cations, Complexation, NMR spectroscopy
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:5
Page Range:pp. 757-771
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000757UNSPECIFIED
ID Code:1677
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Lhoták, Pavel; Šťastný, Václav; Zlatušková, Petra; Stibor, Ivan; Michlová, Veronika; Tkadlecová, Marcela; Havlíček, Jaroslav; Sýkora, Jan (2000) Synthesis and 1H NMR Complexation Study of Thiacalix[4]arene Tetraacetates. Collection of Czechoslovak Chemical Communications, 65 (5). pp. 757-771. ISSN 0010-0765

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