Electrochemical Reduction of Allyl Ethers in the Presence of Nickel Complexes: A Review of Synthetic Applications

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Title:Electrochemical Reduction of Allyl Ethers in the Presence of Nickel Complexes: A Review of Synthetic Applications
Creators:
Olivero, Sandra
Franco, Delphine
Clinet, Jean-Claude
Duñach, Elisabet
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 6, pp. 844-861
Uncontrolled Keywords:Bipyridine ligands, Allyl ethers, Nickel, Protecting groups, Electrochemical reductions, Cleavage, Cyclization

Abstract

This review deals with the electrochemical reactivity of a family of organic compounds, namely allyl ether derivatives, in the presence of various catalytic systems. Essentially, nickel complexes associated with various ligands have been described for such reactions. The electrochemical reduction of allyl aryl ethers has been reported to be very dependent on the nature of the catalytic system. Ni(II) complexes with 2,2'-bipyridine ligands selectively catalyze the cleavage of the O-C(allyl) bond to afford the corresponding alcohol or phenol derivatives in good yields. The related <i>ortho</i>-halogenated allyl ether substrates, in the presence of Ni(II) catalysts with cyclam-type macrocyclic ligands undergo intramolecular cyclizations. The nature of the ligand on nickel strongly influences the reactivity and the chemoselectivity of these processes. A review with 62 references. <p>

Title:Electrochemical Reduction of Allyl Ethers in the Presence of Nickel Complexes: A Review of Synthetic Applications
Creators:
Olivero, Sandra
Franco, Delphine
Clinet, Jean-Claude
Duñach, Elisabet
Uncontrolled Keywords:Bipyridine ligands, Allyl ethers, Nickel, Protecting groups, Electrochemical reductions, Cleavage, Cyclization
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:6
Page Range:pp. 844-861
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000844UNSPECIFIED
ID Code:1684
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Olivero, Sandra; Franco, Delphine; Clinet, Jean-Claude; Duñach, Elisabet (2000) Electrochemical Reduction of Allyl Ethers in the Presence of Nickel Complexes: A Review of Synthetic Applications. Collection of Czechoslovak Chemical Communications, 65 (6). pp. 844-861. ISSN 0010-0765

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