Radical Intermediates in Electrochemical Polymer-Forming Reactions

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Title:Radical Intermediates in Electrochemical Polymer-Forming Reactions
Creators:
Holze, Rudolf
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 6, pp. 899-923
Uncontrolled Keywords:Polyaniline, Radicals, Conducting polymers, Electrochemistry, Intermediates, Spectroelectrochemistry

Abstract

The role of organic radicals in the formation of functional polymers, in particular intrinsically conducting polymers, is reviewed. New results recently obtained with <i>in situ</i> spectroscopic methods illustrating the influence of the molecular structure of monomers (aniline and substituted anilines) in the behaviour of radical intermediates are presented. The stabilising influence of substituents at various positions of the aniline molecule is evaluated and compared based on conceivable structures of reaction intermediates. <p>

Title:Radical Intermediates in Electrochemical Polymer-Forming Reactions
Creators:
Holze, Rudolf
Uncontrolled Keywords:Polyaniline, Radicals, Conducting polymers, Electrochemistry, Intermediates, Spectroelectrochemistry
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:6
Page Range:pp. 899-923
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20000899UNSPECIFIED
ID Code:1687
Item Type:Article
Deposited On:06 Feb 2009 17:11
Last Modified:06 Feb 2009 16:11

Citation

Holze, Rudolf (2000) Radical Intermediates in Electrochemical Polymer-Forming Reactions. Collection of Czechoslovak Chemical Communications, 65 (6). pp. 899-923. ISSN 0010-0765

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