Hydrogenation of 3-(Dimethylamino)propionitrile Over Palladium Catalysts

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Title:Hydrogenation of 3-(Dimethylamino)propionitrile Over Palladium Catalysts
Creators:
Krupka, Jiří
Pašek, Josef
Navrátilová, Markéta
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 65, 11, pp. 1805-1819
Uncontrolled Keywords:Amines, Hydrogenation, Nitriles, Selectivity, 3-(Dimethylamino)propionitrile, Heterogeneous catalysis, Reaction mechanisms, Reductions, Palladium

Abstract

Hydrogenation of 3-(dimethylamino)propionitrile over palladium catalysts was studied. Besides the expected amines, <i>N</i>,<i>N</i>,<i>N'</i>,<i>N'</i>-tetramethylpropane-1,3-diamine, <i>N</i>,<i>N</i>-dimethyl-<i>N'</i>-propylpropane-1,3-diamine, and <i>N</i>,<i>N</i>-bis[3-(dimethylamino)propyl]propylamine were found. Reaction pathways of their formation were discussed. Effects of reaction conditions, type of catalyst, and addition of ammonia or an amine into the charge on the hydrogenation selectivity were studied. <p>

Title:Hydrogenation of 3-(Dimethylamino)propionitrile Over Palladium Catalysts
Creators:
Krupka, Jiří
Pašek, Josef
Navrátilová, Markéta
Uncontrolled Keywords:Amines, Hydrogenation, Nitriles, Selectivity, 3-(Dimethylamino)propionitrile, Heterogeneous catalysis, Reaction mechanisms, Reductions, Palladium
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:65
Number:11
Page Range:pp. 1805-1819
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20001805UNSPECIFIED
ID Code:1760
Item Type:Article
Deposited On:06 Feb 2009 17:12
Last Modified:06 Feb 2009 16:12

Citation

Krupka, Jiří; Pašek, Josef; Navrátilová, Markéta (2000) Hydrogenation of 3-(Dimethylamino)propionitrile Over Palladium Catalysts. Collection of Czechoslovak Chemical Communications, 65 (11). pp. 1805-1819. ISSN 0010-0765

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