Theoretical Analysis of Pulse and Differential Pulse Polarography of Reversible Redox Reaction Complicated by Reactant Adsorption

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Title:Theoretical Analysis of Pulse and Differential Pulse Polarography of Reversible Redox Reaction Complicated by Reactant Adsorption
Creators:
Lovrić, Milivoj
Zelić, Marina
Komorsky-Lovrić, Šebojka
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 66, 3, pp. 423-433
Uncontrolled Keywords:PbBr<sub>2</sub>, Differential pulse polarography, Adsorption, Pulse polarography, Static mercury drop electrode, Stationary spherical diffusion model

Abstract

Pulse and differential pulse polarograms of redox reactions complicated by reactant adsorption with and without lateral attractions in the monolayer are analysed theoretically by using a stationary spherical diffusion model. The continuous shift of the post-peak potential to lower values and the decrease in its half-peak width with increasing bulk concentration of reactant indicate attractions between adsorbed ions or molecules. <p>

Title:Theoretical Analysis of Pulse and Differential Pulse Polarography of Reversible Redox Reaction Complicated by Reactant Adsorption
Creators:
Lovrić, Milivoj
Zelić, Marina
Komorsky-Lovrić, Šebojka
Uncontrolled Keywords:PbBr<sub>2</sub>, Differential pulse polarography, Adsorption, Pulse polarography, Static mercury drop electrode, Stationary spherical diffusion model
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:66
Number:3
Page Range:pp. 423-433
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20010423UNSPECIFIED
ID Code:1798
Item Type:Article
Deposited On:06 Feb 2009 17:12
Last Modified:06 Feb 2009 16:12

Citation

Lovrić, Milivoj; Zelić, Marina; Komorsky-Lovrić, Šebojka (2001) Theoretical Analysis of Pulse and Differential Pulse Polarography of Reversible Redox Reaction Complicated by Reactant Adsorption. Collection of Czechoslovak Chemical Communications, 66 (3). pp. 423-433. ISSN 0010-0765

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