Syntheses of New Triethylene Glycol Bis(alkyl Phosphate)s as Potential Complexing Agents

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Title:Syntheses of New Triethylene Glycol Bis(alkyl Phosphate)s as Potential Complexing Agents
Creators:
Novoměstská, Věra
Herrmann, Eckhard
Lubal, Přemysl
Příhoda, Jiří
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 66, 4, pp. 621-630
Uncontrolled Keywords:Potentiometry, Phosphorylation, Bis(alkyl phosphate), Phosphates, Extraction, O-ligands, Oligoethers, Bis(phosphate), Polyethers

Abstract

A series of triethylene glycol bis(alkyl phosphate)s HO(RO)P(O)(OCH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>OP(O)(OR)OH <strong>4</strong> (R = octyl (<strong>4a</strong>), 1-methylheptyl (<strong>4b</strong>), 2-ethylhexyl (<strong>4c</strong>), nonyl (<strong>4d</strong>), decyl (<strong>4e</strong>), dodecyl (<strong>4f</strong>), hexadecyl (<strong>4g</strong>), octadecyl (<strong>4h</strong>)) has been synthesized with the expectation that these compounds could be effective complexing and/or extraction agents for metal cations. The compounds were characterized by <sup>31</sup>P NMR, <sup>1</sup>H NMR, <sup>13</sup>C NMR and IR spectroscopy, MALDI-TOF mass spectroscopy and elemental analysis. <p>

Title:Syntheses of New Triethylene Glycol Bis(alkyl Phosphate)s as Potential Complexing Agents
Creators:
Novoměstská, Věra
Herrmann, Eckhard
Lubal, Přemysl
Příhoda, Jiří
Uncontrolled Keywords:Potentiometry, Phosphorylation, Bis(alkyl phosphate), Phosphates, Extraction, O-ligands, Oligoethers, Bis(phosphate), Polyethers
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:66
Number:4
Page Range:pp. 621-630
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20010621UNSPECIFIED
ID Code:1815
Item Type:Article
Deposited On:06 Feb 2009 17:12
Last Modified:06 Feb 2009 16:13

Citation

Novoměstská, Věra; Herrmann, Eckhard; Lubal, Přemysl; Příhoda, Jiří (2001) Syntheses of New Triethylene Glycol Bis(alkyl Phosphate)s as Potential Complexing Agents. Collection of Czechoslovak Chemical Communications, 66 (4). pp. 621-630. ISSN 0010-0765

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