Analytical Application of Oligopyrrole Macrocycles

[img]PDF - Authorized users only
Language: English
1158Kb
Title:Analytical Application of Oligopyrrole Macrocycles
Creators:
Záruba, Kamil
Setnička, Vladimír
Charvátová, Jana
Rusin, Oleksandr
Tománková, Zuzana
Hrdlička, Jan
Sýkora, David
Král, Vladimír
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 66, 5, pp. 693-769
Uncontrolled Keywords:Analytical applications, Pyrrols, Self-assembled monolayers, Chromatographic separations, Sapphyrins, DNA binding, Macrocycles, Electronic nose and tongue, Saccharide recognition, Oligopyrroles, Porphyrins, Ion-selective electrodes, Porphyrin receptors, Spectroscopy

Abstract

Progress of modern analytical chemistry is closely related with advancement in other fields such as organic chemistry and biochemistry. Successful solution of current scientific problems is inconceivable without close cooperation of different chemical disciplines. As an example of such hot and very intricate theme research in the field of molecular recognition of biologically active compounds can serve, where numerous methods of analytical chemistry, organic chemistry and biochemistry can suitably be utilized, elaborated and brought into consonance. This multidisciplinary overlap logically leads to the advent of new scientific fields with their own tools, methodologies and subjects of exploration - bioanalytical chemistry and nanotechnology. This review covers different aspects of analytical application of oligopyrrole macrocycles (mainly porphyrins and sapphyrins). These compounds are widely used in analytical chemistry due to their outstanding optical properties. In our contribution oligopyrrole macrocycles are considered as signaling and structural parts of chemical receptors and selectors in various applications. Introduction of different moieties into <i>meso</i>-position of macrocyclic rings allows to obtain <i>e.g.</i>, sterically well-organized receptors for recognition of biologically important analytes, new chromatographic materials, and powerful tools in electrochemical research. Finally, future trends in the field are outlined briefly. <p>

Title:Analytical Application of Oligopyrrole Macrocycles
Creators:
Záruba, Kamil
Setnička, Vladimír
Charvátová, Jana
Rusin, Oleksandr
Tománková, Zuzana
Hrdlička, Jan
Sýkora, David
Král, Vladimír
Uncontrolled Keywords:Analytical applications, Pyrrols, Self-assembled monolayers, Chromatographic separations, Sapphyrins, DNA binding, Macrocycles, Electronic nose and tongue, Saccharide recognition, Oligopyrroles, Porphyrins, Ion-selective electrodes, Porphyrin receptors, Spectroscopy
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:66
Number:5
Page Range:pp. 693-769
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20010693UNSPECIFIED
ID Code:1821
Item Type:Article
Deposited On:06 Feb 2009 17:13
Last Modified:06 Feb 2009 16:13

Citation

Záruba, Kamil; Setnička, Vladimír; Charvátová, Jana; Rusin, Oleksandr; Tománková, Zuzana; Hrdlička, Jan; Sýkora, David; Král, Vladimír (2001) Analytical Application of Oligopyrrole Macrocycles. Collection of Czechoslovak Chemical Communications, 66 (5). pp. 693-769. ISSN 0010-0765

Repository Staff Only: item control page