Separation of Hydrophilic Oligomers and Polymers Using Monodisperse Poly(2,3-dihydroxypropyl Methacrylate-co-Ethylene Dimethacrylate) Beads via Normal-Phase and Hydrophilic-Interaction HPLC

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Title:Separation of Hydrophilic Oligomers and Polymers Using Monodisperse Poly(2,3-dihydroxypropyl Methacrylate-co-Ethylene Dimethacrylate) Beads via Normal-Phase and Hydrophilic-Interaction HPLC
Creators:
Švec, František
Petro, Miroslav
Fréchet, Jean M. J.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 66, 7, pp. 1047-1061
Uncontrolled Keywords:Poly(glycidyl methacrylate-<i>co</i>-ethylene dimethacrylate), Hydrophilic-interaction chromatography, Polymers, Poly(oxyalkylene)s, Stationary phases, Poly(2,3-dihydroxypropyl methacrylate), Polymeric-diol beads, Normal-phase HPLC, Polysaccharides, Cyclodextrins

Abstract

Microparticulate, monosized, and macroporous poly(2,3-dihydroxypropyl methacrylate-<i>co</i>-ethylene dimethacrylate) beads have been used as a stationary phase for HPLC separations of hydrophilic oligomers and polymers. Homogeneous coverage of the sorbent surface with a large number of chemically equivalent diol functionalities affords suitable retentivity in both normal-phase and hydrophilic-interaction chromatographic modes and enables the separations of water-soluble oligomers and polymers. Chromatographic properties of this stationary phase are demonstrated on a variety of separations of poly(oxyalkylene)s, polyvinylpyrrolidones, and polysaccharides. <p>

Title:Separation of Hydrophilic Oligomers and Polymers Using Monodisperse Poly(2,3-dihydroxypropyl Methacrylate-co-Ethylene Dimethacrylate) Beads via Normal-Phase and Hydrophilic-Interaction HPLC
Creators:
Švec, František
Petro, Miroslav
Fréchet, Jean M. J.
Uncontrolled Keywords:Poly(glycidyl methacrylate-<i>co</i>-ethylene dimethacrylate), Hydrophilic-interaction chromatography, Polymers, Poly(oxyalkylene)s, Stationary phases, Poly(2,3-dihydroxypropyl methacrylate), Polymeric-diol beads, Normal-phase HPLC, Polysaccharides, Cyclodextrins
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:66
Number:7
Page Range:pp. 1047-1061
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20011047UNSPECIFIED
ID Code:1842
Item Type:Article
Deposited On:06 Feb 2009 17:13
Last Modified:06 Feb 2009 16:13

Citation

Švec, František; Petro, Miroslav; Fréchet, Jean M. J. (2001) Separation of Hydrophilic Oligomers and Polymers Using Monodisperse Poly(2,3-dihydroxypropyl Methacrylate-co-Ethylene Dimethacrylate) Beads via Normal-Phase and Hydrophilic-Interaction HPLC. Collection of Czechoslovak Chemical Communications, 66 (7). pp. 1047-1061. ISSN 0010-0765

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