The First Synthesis of Geranyllinalool Enantiomers

[img]PDF - Authorized users only
Language: English
93Kb
Title:The First Synthesis of Geranyllinalool Enantiomers
Creators:
Svatoš, Aleš
Urbanová, Klára
Valterová, Irena
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 1, pp. 83-90
Uncontrolled Keywords:Absolute configuration, Cuprates, Terpenoids, Marking pheromones, Carbometallation, Cross-coupling reactions, Bumblebees, Alcohols, Diterpenes

Abstract

(3<i>R</i>)-(-)-Geranyllinalool and its (3<i>S</i>)-(+)-isomer were synthesized in 7 steps starting from both enantiomers of citramalic acid and geranyl bromide. The synthetic sequence established the absolute configurations of naturally occurring geranyllinalools for the first time. <p>

Title:The First Synthesis of Geranyllinalool Enantiomers
Creators:
Svatoš, Aleš
Urbanová, Klára
Valterová, Irena
Uncontrolled Keywords:Absolute configuration, Cuprates, Terpenoids, Marking pheromones, Carbometallation, Cross-coupling reactions, Bumblebees, Alcohols, Diterpenes
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:1
Page Range:pp. 83-90
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20020083UNSPECIFIED
ID Code:1907
Item Type:Article
Deposited On:06 Feb 2009 17:13
Last Modified:06 Feb 2009 16:13

Citation

Svatoš, Aleš; Urbanová, Klára; Valterová, Irena (2002) The First Synthesis of Geranyllinalool Enantiomers. Collection of Czechoslovak Chemical Communications, 67 (1). pp. 83-90. ISSN 0010-0765

Repository Staff Only: item control page