Electrochemical Analysis of Solids. A Review

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Title:Electrochemical Analysis of Solids. A Review
Creators:
Grygar, Tomáš
Marken, Frank
Schröder, Uwe
Scholz, Fritz
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 2, pp. 163-208
Uncontrolled Keywords:Analytical methods, Solid-state chemistry, Voltammetry, Powders, Electrochemistry

Abstract

The topic of the review is the electrochemical analysis of solids aimed to identify or determine their phase or elemental composition, analyse the composition of solid mixtures, characterise their electrochemistry-related properties and analyse the redox state of the constituent elements. The ways of the electrode preparation are discussed with a special attention paid to compact and composite electrodes including carbon-paste electrodes, and direct immobilisation of powders on a working electrode. Examples are given of simultaneous electrochemical measurements combined with X-ray diffraction, optical or atomic force microscopy, and mass measurement by quartz microbalance. The state-of-art of voltammetric analysis of inorganic and organic solids achieved in the last two decades is systematically reviewed with the aim to find cases, when electrochemistry can compete successfully with other analytical techniques as for sensitivity, specificity, and sample consumption. Electrochemical methods are shown to be a perspective tool for redox analysis of catalysts, combined elemental and phase analysis of inorganic pigments and minerals, characterisation of solid solutions, metalloorganic and organic solids. A review with 196 references. <p>

Title:Electrochemical Analysis of Solids. A Review
Creators:
Grygar, Tomáš
Marken, Frank
Schröder, Uwe
Scholz, Fritz
Uncontrolled Keywords:Analytical methods, Solid-state chemistry, Voltammetry, Powders, Electrochemistry
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:2
Page Range:pp. 163-208
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20020163UNSPECIFIED
ID Code:1913
Item Type:Article
Deposited On:06 Feb 2009 17:13
Last Modified:06 Feb 2009 16:13

Citation

Grygar, Tomáš; Marken, Frank; Schröder, Uwe; Scholz, Fritz (2002) Electrochemical Analysis of Solids. A Review. Collection of Czechoslovak Chemical Communications, 67 (2). pp. 163-208. ISSN 0010-0765

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