Vibrational Transition Probabilities and Dissociation Energy of the PF Molecule

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Title:Vibrational Transition Probabilities and Dissociation Energy of the PF Molecule
Creators:
Rajamanickam, Narayanan
Fernandez Gomez, Manuel
Lopez Gonzalez, Juan Jesus
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 58, 4, pp. 748-753

Abstract

The Franck-Condon factors (vibrational transition probabilities) and <i>r</i>-centroids have been evaluated by a more reliable numerical interogation procedure for the bands of <i>b</i><sup>1</sup>Σ<sup>+</sup> - <i>X</i><sup>3</sup>Σ<sup>-</sup> system of the PF molecule, using a suitable potential. The dissociation energy, <i>D</i><sub>e</sub> = 318 kJ mol<sup>-1</sup> for the electronic ground state of this molecule has been estimated by fitting the electronegativity function to the experimental potential energy curve.

Title:Vibrational Transition Probabilities and Dissociation Energy of the PF Molecule
Creators:
Rajamanickam, Narayanan
Fernandez Gomez, Manuel
Lopez Gonzalez, Juan Jesus
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:58
Number:4
Page Range:pp. 748-753
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19930748UNSPECIFIED
ID Code:193
Item Type:Article
Deposited On:06 Feb 2009 16:59
Last Modified:06 Feb 2009 15:59

Citation

Rajamanickam, Narayanan; Fernandez Gomez, Manuel; Lopez Gonzalez, Juan Jesus (1993) Vibrational Transition Probabilities and Dissociation Energy of the PF Molecule. Collection of Czechoslovak Chemical Communications, 58 (4). pp. 748-753. ISSN 0010-0765

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