Selective Cleavage of O-(Dimethoxytrityl) Protecting Group with Sodium Periodate

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Title:Selective Cleavage of O-(Dimethoxytrityl) Protecting Group with Sodium Periodate
Creators:
Rejman, Dominik
Králíková, Šárka
Točík, Zdeněk
Liboska, Radek
Rosenberg, Ivan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 4, pp. 502-508
Uncontrolled Keywords:Lewis acids, Solvent effects, Nucleosides, Catalysis, Oxidations, Deprotection, Dimethoxytrityl, Periodate anions, Protective functions

Abstract

Sodium periodate in aqueous organic solvents selectively removes, under mild reaction conditions, the <i>O</i>-(dimethoxytrityl) protecting group. Selectivity of the cleavage was studied using the nucleoside derivatives protected by various types of groups commonly used in nucleoside and nucleotide chemistry. <p>

Title:Selective Cleavage of O-(Dimethoxytrityl) Protecting Group with Sodium Periodate
Creators:
Rejman, Dominik
Králíková, Šárka
Točík, Zdeněk
Liboska, Radek
Rosenberg, Ivan
Uncontrolled Keywords:Lewis acids, Solvent effects, Nucleosides, Catalysis, Oxidations, Deprotection, Dimethoxytrityl, Periodate anions, Protective functions
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:4
Page Range:pp. 502-508
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20020502UNSPECIFIED
ID Code:1938
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Rejman, Dominik; Králíková, Šárka; Točík, Zdeněk; Liboska, Radek; Rosenberg, Ivan (2002) Selective Cleavage of O-(Dimethoxytrityl) Protecting Group with Sodium Periodate. Collection of Czechoslovak Chemical Communications, 67 (4). pp. 502-508. ISSN 0010-0765

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