Synthesis of Novel o-Carborane-Based Ketonitriles and Their Keto-Enol Tautomerism

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Title:Synthesis of Novel o-Carborane-Based Ketonitriles and Their Keto-Enol Tautomerism
Creators:
Semioshkin, Andrey A.
Inyushin, Sviatoslav G.
Petrovskii, Pavel V.
Bregadze, Vladimir I.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 6, pp. 831-835
Uncontrolled Keywords:Acylation, Boranes, Malononitrile, Enolization, <i>o</i>-Carborane, Carboranes

Abstract

Novel <i>o</i>-carborane-based ketonitriles were obtained in enol form <i>via</i> acylation of malononitrile with 2-methylcarborane-1-carbonyl chloride as well as by acylation of <i>o</i>-carboranylacetonitrile with benzoyl chloride. These ketonitriles appear to exist in solution mostly in enol form. <p>

Title:Synthesis of Novel o-Carborane-Based Ketonitriles and Their Keto-Enol Tautomerism
Creators:
Semioshkin, Andrey A.
Inyushin, Sviatoslav G.
Petrovskii, Pavel V.
Bregadze, Vladimir I.
Uncontrolled Keywords:Acylation, Boranes, Malononitrile, Enolization, <i>o</i>-Carborane, Carboranes
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:6
Page Range:pp. 831-835
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20020831UNSPECIFIED
ID Code:1959
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Semioshkin, Andrey A.; Inyushin, Sviatoslav G.; Petrovskii, Pavel V.; Bregadze, Vladimir I. (2002) Synthesis of Novel o-Carborane-Based Ketonitriles and Their Keto-Enol Tautomerism. Collection of Czechoslovak Chemical Communications, 67 (6). pp. 831-835. ISSN 0010-0765

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