New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane

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Title:New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane
Creators:
Holub, Josef
Jelínek, Tomáš
Janoušek, Zbyněk
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 7, pp. 949-952
Uncontrolled Keywords:Rearrangements, Plešek oxidation, Boranes, <i>closo</i>-Carborane, <i>p</i>-Carborane, Carboranes, <i>nido</i>-Carborane, Ten-vertex

Abstract

Ten vertex <i>p</i>-carborane, 1,10-C<sub>2</sub>B<sub>8</sub>H<sub>10</sub> (<strong>1</strong>), has been prepared in high yield from <i>nido</i>-carborane 5,6-C<sub>2</sub>B<sub>8</sub>H<sub>12</sub> (<strong>2</strong>) in one pot reaction by thermal dehydrogenation followed by skeletal rearrangement. <p>

Title:New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane
Creators:
Holub, Josef
Jelínek, Tomáš
Janoušek, Zbyněk
Uncontrolled Keywords:Rearrangements, Plešek oxidation, Boranes, <i>closo</i>-Carborane, <i>p</i>-Carborane, Carboranes, <i>nido</i>-Carborane, Ten-vertex
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:7
Page Range:pp. 949-952
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20020949UNSPECIFIED
ID Code:1965
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Holub, Josef; Jelínek, Tomáš; Janoušek, Zbyněk (2002) New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane. Collection of Czechoslovak Chemical Communications, 67 (7). pp. 949-952. ISSN 0010-0765

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