4,4'-Bipyridine-2,2',6,6'-tetracarboxamide. Synthesis and Self-Assembling Properties of the Free Base and the 1 : 1 Silver(I) Triflate Complex

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Title:4,4'-Bipyridine-2,2',6,6'-tetracarboxamide. Synthesis and Self-Assembling Properties of the Free Base and the 1 : 1 Silver(I) Triflate Complex
Creators:
Sehnal, Petr
Holý, Petr
Tichý, Miloš
Závada, Jiří
Císařová, Ivana
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 8, pp. 1236-1246
Uncontrolled Keywords:Bipyridines, Biaryls, X-Ray diffraction, Self-assembly, Supramolecular chemistry, Transition metals, Crystal engineering, Amides, Hydrogen bonds

Abstract

Self-assembly of 4,4'-bipyridine-2,2',6,6'-tetracarboxamide and its 1 : 1 silver(I) triflate complex was investigated by single crystal X-ray diffraction analysis. It was found that intermolecular amide-amide hydrogen bonds control the crystal packing of the free base giving rise to infinite zig-zag tapes, whereas an octahedral coordination of the Ag(I) ion with the ligand dominates in the packing of the corresponding complex. <p>

Title:4,4'-Bipyridine-2,2',6,6'-tetracarboxamide. Synthesis and Self-Assembling Properties of the Free Base and the 1 : 1 Silver(I) Triflate Complex
Creators:
Sehnal, Petr
Holý, Petr
Tichý, Miloš
Závada, Jiří
Císařová, Ivana
Uncontrolled Keywords:Bipyridines, Biaryls, X-Ray diffraction, Self-assembly, Supramolecular chemistry, Transition metals, Crystal engineering, Amides, Hydrogen bonds
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:8
Page Range:pp. 1236-1246
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20021236UNSPECIFIED
ID Code:1987
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Sehnal, Petr; Holý, Petr; Tichý, Miloš; Závada, Jiří; Císařová, Ivana (2002) 4,4'-Bipyridine-2,2',6,6'-tetracarboxamide. Synthesis and Self-Assembling Properties of the Free Base and the 1 : 1 Silver(I) Triflate Complex. Collection of Czechoslovak Chemical Communications, 67 (8). pp. 1236-1246. ISSN 0010-0765

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