Synthesis of α-Fluoro-β-lactones and Their Thermal Conversion to 1-Fluoroalkenes

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Title:Synthesis of α-Fluoro-β-lactones and Their Thermal Conversion to 1-Fluoroalkenes
Creators:
Ocampo, Rogelio
Dolbier, William R.
Zuluaga, Fabio
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 9, pp. 1325-1334
Uncontrolled Keywords:Thermolysis, Hydroxy acids, Fluorine, Alkenes, Decarboxylation, β-Lactones, Fluoroalkenes

Abstract

α-Fluoro-β-lactones have been synthesized and isolated for the first time from α-fluoro-β-hydroxy acids by using the couple TsCl/DMAP as lactonization agent. A detailed description of the synthesis and spectroscopic properties of α-fluoro-β-lactones is presented. Preliminary results indicate that thermolysis of these new β-lactones produces 1-fluoroalkenes. <p>

Title:Synthesis of α-Fluoro-β-lactones and Their Thermal Conversion to 1-Fluoroalkenes
Creators:
Ocampo, Rogelio
Dolbier, William R.
Zuluaga, Fabio
Uncontrolled Keywords:Thermolysis, Hydroxy acids, Fluorine, Alkenes, Decarboxylation, β-Lactones, Fluoroalkenes
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:9
Page Range:pp. 1325-1334
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20021325UNSPECIFIED
ID Code:1996
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Ocampo, Rogelio; Dolbier, William R.; Zuluaga, Fabio (2002) Synthesis of α-Fluoro-β-lactones and Their Thermal Conversion to 1-Fluoroalkenes. Collection of Czechoslovak Chemical Communications, 67 (9). pp. 1325-1334. ISSN 0010-0765

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