Use of Fluorinated Organic Compounds in Living Radical Polymerizations

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Title:Use of Fluorinated Organic Compounds in Living Radical Polymerizations
Creators:
Lacroix-Desmazes, Patrick
Améduri, Bruno
Boutevin, Bernard
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 10, pp. 1383-1415
Uncontrolled Keywords:Fluorinated polymers, Reversible addition-fragmentation chain transfer, Atom transfer radical polymerization, Nitroxide, Fluoromonomers, Fluorinated compounds, Living free radical polymerization, Iodine transfer polymerization, Iniferter

Abstract

Controlled/living radical polymerization (LRP) is a field of special interest because it allows tailoring well-defined macromolecular architectures such as telechelic, block, graft or star copolymers. Since the eighties, several techniques have been reported [such as the iniferter method, nitroxide-mediated radical polymerization (NMP), atom transfer radical polymerization (ATRP), iodine transfer polymerization (ITP), and reversible addition-fragmentation chain transfer (RAFT)] giving rise to a huge number of publications and patents. This review aims at illustrating the contribution of fluorinated organic compounds in this area of research through the use of fluorinated initiators (dithiocarbamates, xanthates, tetraphenylethanes, alkoxyamines, fluorinated alkyl halides, and dithioesters) or other fluorinated molecules (ligands, solvents). Another point depicts the LRP of various fluorinated monomers (methacrylates, acrylates, styrenics, and alkenes). Finally, fluorinated block and graft copolymers prepared by LRP have been reported. A review with 165 references. <p>

Title:Use of Fluorinated Organic Compounds in Living Radical Polymerizations
Creators:
Lacroix-Desmazes, Patrick
Améduri, Bruno
Boutevin, Bernard
Uncontrolled Keywords:Fluorinated polymers, Reversible addition-fragmentation chain transfer, Atom transfer radical polymerization, Nitroxide, Fluoromonomers, Fluorinated compounds, Living free radical polymerization, Iodine transfer polymerization, Iniferter
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:10
Page Range:pp. 1383-1415
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20021383UNSPECIFIED
ID Code:2002
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Lacroix-Desmazes, Patrick; Améduri, Bruno; Boutevin, Bernard (2002) Use of Fluorinated Organic Compounds in Living Radical Polymerizations. Collection of Czechoslovak Chemical Communications, 67 (10). pp. 1383-1415. ISSN 0010-0765

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