Coordination Cadmium Compounds with 1,10-Phenanthroline

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Title:Coordination Cadmium Compounds with 1,10-Phenanthroline
Creators:
Weiguang, Zhang
Xuhong, Jiang
Yun, Zhong
Mingyu, Tan
Suelein, Wang
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 11, pp. 1623-1628
Uncontrolled Keywords:Xanthates, X-Ray diffraction, Cadmium(II) complexes, Chelates, 1,10-Phenanthroline, Crystal structure

Abstract

[Cd(R-XA)<sub>2</sub>]<i><sub>n</sub></i> (XA = xanthate; R = Et, Bu) transformed upon reaction with 1,10-phenanthroline (phen) to [Cd(R-XA)<sub>2</sub>(phen)]. The product with R = Et crystallizes in the orthorhombic space group <i>Pbcn</i>, while that with R = Bu belongs to the monoclinic system, space group <i>C</i>2/<i>c</i>. In two complexes, adjacent phenanthroline ligands form a layered array due to mutual π-π interactions. <p>

Title:Coordination Cadmium Compounds with 1,10-Phenanthroline
Creators:
Weiguang, Zhang
Xuhong, Jiang
Yun, Zhong
Mingyu, Tan
Suelein, Wang
Uncontrolled Keywords:Xanthates, X-Ray diffraction, Cadmium(II) complexes, Chelates, 1,10-Phenanthroline, Crystal structure
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:11
Page Range:pp. 1623-1628
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20021623UNSPECIFIED
ID Code:2020
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Weiguang, Zhang; Xuhong, Jiang; Yun, Zhong; Mingyu, Tan; Suelein, Wang (2002) Coordination Cadmium Compounds with 1,10-Phenanthroline. Collection of Czechoslovak Chemical Communications, 67 (11). pp. 1623-1628. ISSN 0010-0765

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