Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate

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Title:Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate
Creators:
Xuhong, Jiang
Weiguang, Zhang
Yun, Zhong
Suelein, Wang
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 11, pp. 1629-1634
Uncontrolled Keywords:Xanthates, X-Ray diffraction, Silver(I) complexes, Crystal structure, Two-dimensional polymers, Butyl xanthate

Abstract

Polymeric silver(I) butyl xanthate, [Ag(Bu-XA)]<i><sub>n</sub></i>, was synthesized and crystallographically characterized. The polymer shows chair conformation of eight-membered ring units and a novel mode of coordination, with a structural arrangement different from that in silver dialkyldithiocarbamate and dialkyldithiophosphates. The polymeric structure of the new complex is formed by corrugated planes. <p>

Title:Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate
Creators:
Xuhong, Jiang
Weiguang, Zhang
Yun, Zhong
Suelein, Wang
Uncontrolled Keywords:Xanthates, X-Ray diffraction, Silver(I) complexes, Crystal structure, Two-dimensional polymers, Butyl xanthate
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:11
Page Range:pp. 1629-1634
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20021629UNSPECIFIED
ID Code:2021
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:14

Citation

Xuhong, Jiang; Weiguang, Zhang; Yun, Zhong; Suelein, Wang (2002) Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate. Collection of Czechoslovak Chemical Communications, 67 (11). pp. 1629-1634. ISSN 0010-0765

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