Derivatives of (S)-{[2-(Methoxymethyl)pyrrolidin-1-yl]methyl}ferrocene - New Planar Chiral Ligands

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Title:Derivatives of (S)-{[2-(Methoxymethyl)pyrrolidin-1-yl]methyl}ferrocene - New Planar Chiral Ligands
Creators:
Šebesta, Radovan
Sališová, Marta
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 67, 11, pp. 1700-1708
Uncontrolled Keywords:Planar chirality, Asymmetric catalysis, Amino alcohols, Ferrocenes, Metallocenes, Diethylzinc addition, Ferrocenyl ligands

Abstract

New planar chiral amino-alcohol ferrocene ligands based on (<i>S</i>)-2-(methoxymethyl)pyrrolidine were synthesized and employed in the enantioselective addition of diethylzinc to benzaldehyde with enantioselectivity up to 82%. The effect of planar chirality was evaluated. <p>

Title:Derivatives of (S)-{[2-(Methoxymethyl)pyrrolidin-1-yl]methyl}ferrocene - New Planar Chiral Ligands
Creators:
Šebesta, Radovan
Sališová, Marta
Uncontrolled Keywords:Planar chirality, Asymmetric catalysis, Amino alcohols, Ferrocenes, Metallocenes, Diethylzinc addition, Ferrocenyl ligands
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:67
Number:11
Page Range:pp. 1700-1708
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20021700UNSPECIFIED
ID Code:2027
Item Type:Article
Deposited On:06 Feb 2009 17:14
Last Modified:06 Feb 2009 16:15

Citation

Šebesta, Radovan; Sališová, Marta (2002) Derivatives of (S)-{[2-(Methoxymethyl)pyrrolidin-1-yl]methyl}ferrocene - New Planar Chiral Ligands. Collection of Czechoslovak Chemical Communications, 67 (11). pp. 1700-1708. ISSN 0010-0765

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