A Facile Synthesis of Selectively Protected Linear Oligoamines

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Title:A Facile Synthesis of Selectively Protected Linear Oligoamines
Creators:
Koščová, Simona
Buděšínský, Miloš
Hodačová, Jana
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 68, 4, pp. 744-750
Uncontrolled Keywords:Building blocks, Amines, Azacrown macrocycles, Protecting groups, Polyamines, NMR spectroscopy

Abstract

A convenient multi-gram preparative method for the synthesis of linear oligoamines having the terminal primary amino groups unprotected and the central secondary amino functions protected with <i>tert</i>-butoxycarbonyl groups is presented. At the same time, simple one-pot preparation of the α,ω-bis(trifluoroacetamide) intermediates <strong>2</strong> has been developed. NMR spectra of the novel selectively protected oligoamines are also discussed. <p>

Title:A Facile Synthesis of Selectively Protected Linear Oligoamines
Creators:
Koščová, Simona
Buděšínský, Miloš
Hodačová, Jana
Uncontrolled Keywords:Building blocks, Amines, Azacrown macrocycles, Protecting groups, Polyamines, NMR spectroscopy
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:68
Number:4
Page Range:pp. 744-750
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20030744UNSPECIFIED
ID Code:2081
Item Type:Article
Deposited On:06 Feb 2009 17:15
Last Modified:06 Feb 2009 16:15

Citation

Koščová, Simona; Buděšínský, Miloš; Hodačová, Jana (2003) A Facile Synthesis of Selectively Protected Linear Oligoamines. Collection of Czechoslovak Chemical Communications, 68 (4). pp. 744-750. ISSN 0010-0765

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